/bartender is for the addon Bartender's command line options.
/carb or /carbonite is a valid Carbonite command line.
Carbonite does not come with action bar buttons. It's a Map/Questing/Pvp addon. Press "M" to open the map, L to open the Carb Quest Log, or type /carb options to see all the options. Provided that Carb is setup to default bindings.
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