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When my hubby and I used to share a computer, we just kept two different copies of the Interface folder and swapped them depending on who was going to play. So... If I was going to play, there would be WoW\Interface and WoW\Interface_his folders. When he wanted to play, he would rename my Interface folder to Interface_hers and rename his to just Interface. For the WTF folder, it does not matter because it stores settings per account anyway.
You have to log out to switch accounts anyway, may as well completely exit to desktop so that you can get the new folder of addons.
This is the easiest, most fool-proof way that most people use. Well, and the having two copies of WoW suggestion, though not everyone has the hard drive space for that.
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"You'd be surprised how many people violate this simple principle every day of their lives and try to fit square pegs into round holes, ignoring the clear reality that Things Are As They Are." -Benjamin Hoff, The Tao of Pooh
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