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If you use Wowhead, and browse 'Quests', there is a button on the right side for filters. You can filter quests for horde, raise faction with, Orgrimmar. It will list all the quest that gives Org rep.
In addition to those, I think it is level 10 quests that gives starting city rep, will get you some spill over. I think it is 25%. So if you do a quest that gives 250 Undercity rep, you will get about 63 rep in each of the other faction. I did notice this is not 100% and have not found a reason why some give spill over and others dont. Basically, do as many quests level 10+ for all the reps, and the level 1 starting quests for Orgrimmar.
I have 3 Blood Elves that got exalted with UC by level 40.
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