Actually, in the case of the nUI_AuraButtons plugin, you wouldn't be editing the layout files in the [ Interface > AddOns > nUI ] directory tree because that is being overwritten by the plugin. Rather, you would edit [ Interface > AddOns > nUI_AuraButtons > nUI_AuraButtons.lua ]
However, aside from that, NeuralAssassin is correct... you want to look for the "anchor =" sections and alter the values of "xOfs" to move the aura group left and right or alter "yOfs" to move it up and down.
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