I had downloaded a random ui a while ago, and it had one little addon that was splitting the screen into little squares/lines or something, so that you could position/center the interface's elements.
Align. Looks like the last update was 08/05/2009, but I use it and it still works fine. If you're really picky about lining up your UI elements, you could also use Lineem Up. Also a bit out-of-date, but still works fine.
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"You'd be surprised how many people violate this simple principle every day of their lives and try to fit square pegs into round holes, ignoring the clear reality that Things Are As They Are." -Benjamin Hoff, The Tao of Pooh